💥 NON-STANDARD MATERIALS · QUICK REFERENCE

Non-Standard Materials
Quick Reference

Deep hole drilling parameters for the materials that don’t behave — gummy copper, pyrophoric magnesium and zirconium, abrasive graphite, fiber-tearing composites, work-hardening superalloys. Start at the lower bound, verify chip form, then climb.

15+MaterialsExotic & non-ferrous
3 TiersDifficultyCut, fire & wear risk
10–200Vc m/minRange across table
Mg / ZrChip riskPyrophoric fines

30-Second Summary

One table, four rules, and most of the trouble is over.

RuleWhy It Matters
Start from the lower bound of Vc and feedEvery material in this table punishes overconfidence. The low end is safe; the high end is where you optimize after proof.
Never use water-based coolant on magnesium or zirconiumMagnesium reacts with water to produce flammable hydrogen gas; fine zirconium chips are pyrophoric. Dry machining or oil-based coolant only.
Raise feed on copper to force thick, breakable chipsLow feed on gummy copper produces long stringy tangles that pack the flute and seize the drill.
Inspect chip form on every trial cutChip shape is the feedback loop. Short, broken, consistent chips mean a stable process; ribbons, powders, or balled chips mean stop and adjust.
🔧
First-Article Procedure

1. Find the closest material group. 2. Take the lower bound of Vc and feed. 3. Trial-cut 10–20 mm, inspect chip shape and surface. 4. Optimize incrementally from chip condition. Watch the first 5–10 holes for tool-wear patterns before raising throughput.

⚠️
Risk Is Not Uniform

Machinability and hazard are two different axes. Magnesium cuts beautifully but ignites; graphite machines fast but coats every surface in conductive dust. Grade each material on difficulty and risk before you load the machine.

💡 Key takeaway: This page is a starting reference. Gundrill and BTA insert geometry, machine rigidity, coolant chemistry and hole diameter all shift the sweet spot. When a material is unfamiliar, budget for a parameter-development pass — it pays for itself in the first 50 holes.

Exotic & Non-Standard Materials

MaterialDifficultyTypical GradeVc (m/min)Feed* (mm/rev)Coolant PressureNotes
Copper (pure)ModerateC110, C10160–1200.02–0.1030–50 barGummy, long stringy chips. Raise feed to make thick breakable chips. Coolant at 20–22°C, filtration <20 μm. IT8–IT9 achievable. EP oil, sharp polished edges, positive rake.
BrassEasyC360 (free-cutting)80–1500.02–0.0820–40 barEasiest of the copper family — C360 is the 100% machinability benchmark. Watch for burrs at exit. Lead improves chip breaking; reduce Vc ~20% on dezincification-resistant grades.
BronzeDifficultC932 (SAE 660)60–1000.02–0.0630–50 barAbrasive high-tin alloy, faster tool wear. Use K-grade carbide. Aluminum bronzes are more abrasive than tin bronzes; phosphor bronze (C510) is the worst.
Magnesium alloyEasy cut · fire riskAZ31, AZ91100–2000.05–0.1520–30 bar (oil or dry)⚠️ No water-based coolant — produces hydrogen gas. Dry or light mineral oil only. Sharp tooling, heavy feed for thick chips. Class D extinguisher + dry sand on hand.
Nickel-based alloyDifficultMonel 40020–350.01–0.03≥80 barSevere adhesion and work hardening. Polished rake face reduces material pickup. Continuous feed is mandatory — no dwell, no rubbing.
Cobalt-based alloyExtremeStellite 6B15–250.01–0.02≥100 barExtremely wear-resistant. PCBN tooling recommended for production; carbide feasible for short runs with short life.
Tool steel (annealed)ModerateD2, O1, A250–700.02–0.0560–100 barHigh carbide content — D2 carries ~12% Cr and machines at ~35% of W1. Monitor guide-pad wear. AlTiCrN coating recommended.
Tool steel (hardened)ExtremeD2 (HRC 58–62)15–250.01–0.03≥80 barPCBN or CBN-coated tooling only. See the hardened-steel guide for detail.
Maraging steelDifficultC300, C35030–500.015–0.04≥80 barHigh toughness. Excellent finish possible — Ra <0.4 μm with stable cutting. Maintain continuous feed.
Carburized steel (post-case)Difficult20CrMnTi, 862020–350.01–0.03≥80 barHard surface (>HRC 58) over a tough core. Reduce feed ~20% crossing the case-to-core transition zone.
Tungsten carbide (green)ExtremeWC-Co (pre-sintered)10–200.005–0.01530–50 barExtremely abrasive. Diamond / PCD tooling mandatory. High-volume coolant flushes the slurry. Never drill sintered (finished) carbide.
Powder metallurgyModerateVarious30–600.02–0.0530–60 barPorosity changes thermal conductivity. Avoid excessive coolant pressure that could impregnate pores. Exit burr formation is unpredictable.
Plastic / CompositeDifficultPEEK, CFRP, GFRP50–1500.01–0.0510–20 bar (air or mist)Delamination risk at entry and exit. PCD tooling for production. Support board at exit; reduce feed at exit to prevent fiber tear-out.
TantalumExtremeTa, Ta-10W15–300.01–0.03≥80 barHigh density, high melting point, gummy. Sharp tooling and continuous feed. High coolant pressure essential to lift chips out of deep holes.
ZirconiumDifficult · fire riskZr 702, Zr 70525–450.01–0.04≥60 barFine chips are pyrophoric like titanium. No water-based coolant — oil-based only. Operation falls under NFPA 484 (combustible metals).

* Feed reference values for D = 10 mm. For smaller diameters reduce feed proportionally; for larger diameters increase. Difficulty grades the machining window, not the safety risk — see the Safety section for fire and dust hazards.

Copper, Brass & Bronze

The gummy family: great conductivity, terrible chip behavior. Chip control — not cutting force — is the real problem.

AlloyMachinabilityPoint AngleCoolantKey Behavior
Pure copper (C110, C101)~20%100°EP oil, 30–50 barBuilt-up edge and stringy chips; copper does not like slow speeds. Sharp, polished, positive-rake edges; uncoated carbide often outlasts coated on copper.
Free-cutting brass (C360)100% (benchmark)118°Dry or soluble oilDrills dry or with soluble oil. Lead gives clean chip breaking; non-leaded brasses are markedly harder.
Bronze (C932 SAE 660)20–80%118°Soluble oil, 30–50 barHarder and more abrasive than brass — high tin and phosphor content wear carbide fast. K-grade carbide preferred.

Oxygen-free copper at high L/D

Research on large-aspect-ratio deep drilling of oxygen-free copper (RSM + genetic-algorithm optimization) found feed rate is the single most influential parameter, ahead of cutting speed and coolant pressure. Optimal windows landed near Vc 47 m/min, feed 0.019–0.023 mm/rev, and fluid pressure 2.1–2.4 MPa (21–24 bar), with the speed × pressure interaction dominating chip evacuation. Practical takeaway: on copper, tune feed first and keep coolant temperature steady at 20–22°C.

⚠️ Beryllium copper: Machining BeCu releases toxic dust. Flood-coolant wet cutting is mandatory, with proper extraction and OSHA-compliant exposure control — never dry-machine beryllium copper.
💡 Chip-breaker help: Copper and other ductile alloys produce continuous chips that jam the flute. Chip-splitter and groove-type breaker geometries (ISCAR ICG/TOGT, Tungaloy NDL) segment long chips for reliable evacuation — a groove-type breaker on tough steel shortened chips from 25–80+ mm to under 10 mm while cutting axial force ~10–13% and torque ~13–19%.

Fast, Light & Combustible

Magnesium cuts like a dream and burns like a flare. The machining window is wide; the safety envelope is narrow.

75–400
SFM
Drill speeds (300–600 SFM reported)
40–45°
Helix
High-helix drills to lift chips
473°C
Ignition
Chips and fines ignite; dust flashes
<4%
H₂ LEL
Keep hydrogen below explosion limit

Parameters

🔥 Fire response: Magnesium chips ignite at ~473°C. Keep a Class D extinguisher (dry powder) and dry sand within reach. Never use water, foam, CO₂ or Halon — they react violently and intensify the fire. Cover and smother burning swarf; do not blast it, which spreads the fire. Store chips dry in sealed, vented steel containers (three ~25 mm vent holes keep hydrogen below the 4% lower explosion limit).
⚠️ Housekeeping: Clean the machine at least once per shift. Keep magnesium chips dry and separated from other metals — wet contact with dissimilar metals can generate hydrogen by galvanic corrosion. Use explosion-proof motors and vacuums where fine dust settles.

Tool, Maraging & Case-Hardened Steels

High-carbide and high-toughness steels that trade cutting ease for wear resistance. Drill them in the softest condition you can schedule.

ConditionToolingVc (m/min)Feed (mm/rev)Practical Note
D2 annealed (~210–250 HB)Carbide-tipped or solid carbide, AlTiCrN35–50 (carbide); ~10 HSS0.08–0.25 (conventional)D2 machines at ~35% of W1 due to chromium carbides. Gundrill before hardening whenever possible; split-point geometry stops walking.
D2 hardened (58–62 HRC)PCBN / CBN-coated15–250.01–0.03PCBN hard machining runs 70–120 m/min on turning but drilling keeps speeds low. Expect Ra 0.12–0.28 μm on finish passes.
Maraging C300/C350Carbide, continuous feed30–500.015–0.04High toughness, gummy if feed stalls. Continuous feed prevents local hardening; Ra <0.4 μm is achievable.
Carburized 8620 / 20CrMnTiCarbide, coated20–350.01–0.03Hard case >HRC 58 over a tough core. Reduce feed ~20% as the tool crosses from case to core.
⚠️ Watch the guide pads: D2’s chromium carbide precipitates act as an abrasive lapping compound on guide pads and carbide bushings. Inspect pads every few holes on long runs — pad wear is the first symptom of an out-of-tolerance bore.
💡 Rule of thumb: Machine tool steel to near-net, then harden, then grind/finish the bore. Drilling hardened D2 is a last resort reserved for rework — it demands PCBN and extremely rigid setup.

Monel, Hastelloy, Inconel & Stellite

Work-hardening superalloys where chip evacuation and heat management decide everything. Coolant pressure is the first knob to turn.

MaterialVc (m/min)Feed (mm/rev)CoolantTooling / Notes
Monel 40020–310.01–0.03≥80 barSevere adhesion; polished rake face, high-pressure oil. Consistent feed prevents work-hardening the cut zone.
Nickel-base (Inconel, Hastelloy, Waspaloy, Rene)22–35 (<40 HRC); 18–31 (>40 HRC)0.010–0.076 by diameterUp to 100 barCarbide, then PCBN gun drills for throughput. Full-heat-treated precipitation-strengthened grades are harder than solution-treated.
Stellite 6B (cobalt-base)15–250.01–0.02≥100 barPCBN for production; carbide for short runs only.

Why chip evacuation dominates

Without proper chip evacuation, gun drills fail under intense thermal and mechanical loading in Inconel-class alloys; chips pack, recut, score the bore and cause dimensional taper. High-pressure through-tool coolant is the mechanism — providers report 80–100 bar on Hastelloy and Inconel, and small-diameter Inconel 718 gun drilling at extreme L/D cites at least 500–1000 psi (35–70 bar). Coolant demand scales with depth: extended-length toolholders multiply required pressure and flow roughly in proportion to extension (a 3XL holder ~3×).

💡 First sign of trouble: On superalloys, a sudden coolant-pressure drop means blocked chips — retract immediately, clear, and check the bore before continuing. Pressure stability is the process alarm.

PEEK, CFRP & GFRP

Abrasive fibers, soft matrix, and two failure modes — delamination at entry/exit and melting at the cutting edge. Heat and thrust are the enemies.

MaterialVc (m/min)Feed (mm/rev)CoolantTooling
PEEK (pure)30–600.02–0.10Strong air or MQLCarbide, 118–130° point, polished flutes; frequent retraction for deep holes
PEEK GF30 / CF30Lower than pure0.01–0.05Air / mistPCD or diamond-coated — fibers destroy carbide quickly
CFRP / GFRP50–1500.01–0.0510–20 bar air or mist; vacuum extractionPCD / diamond-coated mandatory; carbide wears fast on carbon and glass fibers

Delamination control

⚠️ Heat control in PEEK: PEEK’s glass-transition temperature is only ~143°C. Overheating softens the matrix, causes burrs, melting and delamination. Use air or MQL — flood coolant is not needed — and retract frequently on deep holes to clear chips before they melt.
⚠️ Health hazard: CFRP and GFRP dust is a respiratory hazard. Vacuum extraction at the cut zone is mandatory — never blow carbon dust into the shop air.

Graphite & Carbon Electrode

Graphite makes powder, not chips — fine, abrasive, electrically conductive dust that ruins machines and lungs if not captured.

Hole SizeToolingSpeedTechnique
≤1.5 mmHSS (carbide is brittle at this size)~4,000 rpmSlow feed; check taper frequently — HSS wears quickly on graphite
>1.5 mmSolid carbide, preferably diamond-coated900–2,000 rpmDiamond/PVD coatings give 8–30× the life of uncoated; PCD tips last longest
Large core holesCarbide125–600 rpmHand-feed entry at ~125 rpm, then raise; vacuum collection
⚠️ Fire risk: Fine graphite powder is combustible. Dust collection should discharge safely (water-precipitation collectors are standard for combustible-metal/graphite dust), and housekeeping must prevent powder accumulation on hot surfaces and electrical gear.

Tantalum, Zirconium & Carbide

Gummy refractory metals with high melting points — and fire rules that are not optional. Zirconium and tantalum machining falls under NFPA 484 (combustible metals).

MaterialVc (m/min)Feed (mm/rev)CoolantBehavior
Tantalum, Ta-10W15–300.01–0.03≥80 barHigh density, high melting point, gummy. Sharp tooling, continuous feed, high-pressure oil to lift chips out of the bore.
Zirconium, Zr 702/70525–450.01–0.04≥60 bar, oil-based onlyFine chips and fines are pyrophoric. Never water-based coolant. Store chips sealed and dry; Class D fire plan in force.
Tungsten carbide (green)10–200.005–0.01530–50 bar, high volumeExtremely abrasive pre-sintered block. PCD tooling mandatory; flood the slurry out. Never on sintered carbide.
Powder metallurgy30–600.02–0.0530–60 barPorosity changes thermal behavior; avoid pressure that impregnates pores. Exit burrs vary.
🔥 Class D fires: Combustible-metal fires (zirconium, tantalum, magnesium) burn at 1,800–7,000°F and are dangerous to approach. Zirconium fires are not fought with water or CO₂ — Class D dry powder or inert gas (argon/helium) is the response. Water on burning metal can generate hydrogen and self-fuel the reaction.
⚠️ Coolant choice: For refractory metals, engineered metalworking fluids that are nonflammable, nonreactive and thermally stable are preferred — they lubricate and cool without adding a Class B oil-fire hazard on top of the Class D risk.

The Two Levers That Fix Most Problems

Virtually every failure on non-standard materials traces back to a chip that could not form or could not leave. Chip geometry and coolant pressure are where you intervene.

🔄
Chip Breakers

Ductile materials (copper, aluminum, tough steels) need chip-splitting or groove-type breakers to segment long ribbons. A groove-type breaker on tough steel shortened chips from 25–80+ mm to under 10 mm and roughly halved tool wear; ISCAR’s splitter and Tungaloy’s NDL geometries are designed for low-feed gun-drill machines (≤0.1 mm/rev).

🔍
Coolant Pressure Scales With Depth

Extended-length holders multiply the required pressure and flow roughly in proportion to extension — a 3XL holder needs ~3× the pressure and flow of a standard holder. Plan coolant capacity for the deepest hole, not the typical one. Filtration matters too: copper builds up on bearing pads at >20 μm contamination.

FaultMaterial SymptomFix
Long stringy chipsPure copper, aluminum, tough steelsRaise feed, add chip-splitter / groove breaker geometry
Built-up edgeCopper, Monel, low-ductility alloysEP coolant, sharp polished positive-rake edges, adequate chip load
Powder / fine chipsMagnesium, zirconium, graphiteHeavier feed for thicker chips; sharp tools; watch ignition risk
Sudden coolant pressure dropAll deep-hole materialsBlocked chip train — retract, clear, inspect bore
Exit delamination / tear-outCFRP, GFRP, PEEKReduce feed at exit, support board, larger point angle
Guide-pad wearD2, bronze, graphiteCleaner filtration, coated pads, higher-pressure flush

Fire, Dust & Chip Handling

🔥 Pyrophoric materials: Magnesium and zirconium produce fine chips that can ignite spontaneously in air. Never use water-based coolant on either — magnesium reacts with water to release flammable hydrogen gas. Dry machining or oil-based coolant only. Keep Class D extinguishers and dry sand accessible; store chips in sealed, vented steel containers.
⚠️ Toxic / conductive dust: Beryllium copper (toxic), graphite (conductive, respirable), and carbon fiber (respirable) all demand extraction at the source. Water-curtain traps and HEPA-filtered vacuums keep the shop safe and the machine running.
⚠️ High-pressure coolant: Lines at 80–100 bar are lethal if disconnected under pressure. Relieve at the pump before maintenance; use whip-checks on high-pressure hoses; never defeat interlocks.
💡 Recovery plan: Before production on an unfamiliar material, write the tool-breakage recovery procedure — how to clear a broken gun drill from the bore without scrapping the part. Torque and coolant-pressure monitoring with automated retract is the industry-standard safeguard on superalloys.

Parameters Are Starting Points

Published numbers vary by tool maker, machine, coolant and geometry — treat every cell in this page as a launch point, not a specification.

⚠️ Warning: Cutting speed is set primarily by the alloy; feed is set by the drill diameter; coolant pressure is set by depth and chip form. Do not transfer parameters between alloy families — nickel-base superalloys, titanium, 300M-class steels and aluminum each behave differently even at similar hardness. Never run production on a new material without trial cuts, first-article inspection, and a documented parameter-development pass.
💡 Reference catalog: For production gundrill data on exotic alloys, consult the tool manufacturers directly — Botek, TBT and Eldorado/Star Cutter catalogs carry diameter-specific speeds, feeds and coolant rates that generic tables cannot. ISCAR’s deep-hole drilling handbook is a solid second source.

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